Metal substitution could improve thin films

The advance, described in a paper published in Inorganic Chemistry, is said to represent a new approach to transmetalation, a process in which individual atoms of one metal complex - a cluster in this case - are individually substituted in water.

For this study, Maisha K. Kamunde-Devonish and Milton N. Jackson Jr., doctoral students in the Department of Chemistry and Biochemistry, replaced aluminium atoms with indium atoms.

The goal is to develop inorganic clusters as precursors that result in dense thin films with negligible defects, resulting in new functional materials and thin-film metal oxides. The latter would have wide application in a variety of electronic devices.

‘Since the numbers of compounds that fit this bill is small, we are looking at transmetelation as a method for creating new precursors with new combinations of metals that would circumvent barriers to performance,’ Kamunde-Devonish said in a statement.

Components in these devices now use deposition techniques that require a lot of energy in the form of pressure or temperature. Doing so in a more environmentally way - reducing chemical waste during preparation - could reduce manufacturing costs and allow for larger-scale materials, she said.

‘In essence we can prepare one type of nanoscale cluster compound, and then step-by-step substitute out the individual metal atoms to make new clusters that cannot be made by direct methods,’ said co-author Darren W. Johnson, a professor of chemistry. ‘The cluster we report in this paper serves as an excellent solution precursor to make very smooth thin films of amorphous aluminium indium oxide, a semiconductor material that can be used in transparent thin-film transistors.’

Transmetalation normally involves a reaction done in organic chemistry in which the substitution of metal ions generates new metal-carbon bonds for use in catalytic systems and to synthesize new metal complexes.

‘This is a new way to use the process,’ Kamunde-Devonish said, ‘Usually you take smaller building blocks and put them together to form a mix of your basic two or three metals. Instead of building a house from the ground up, we’re doing some remodelling. In everyday life that happens regularly, but in chemistry it doesn’t happen very often. We’ve been trying to make materials, compounds, anything that can be useful to improve the processes to make thin films that find application in a variety of electronic devices.’

The process, she added, could be turned into a toolbox that allows for precise substitutions to generate specifically desired properties.

‘Currently, we can only make small amounts but the fact that we can do this will allow us to get a fundamental understanding of how this process happens,’ she said. ‘The technology is possible already. It’s just a matter of determining if this type of material we’ve produced is the best for the process.’